Knock Wood, Here Comes Charlie The Munsters : Season 1 Episode 9

Herman has a twin brother Charlie who is a con-artist. He comes to town and ends up stays at the Munster home, which doesn't make Herman too happy. Charlie claims to have made an invention that takes uranium from seawater, he's looking for an investor. Herman thinks that the whole thing is a scheme to get a Lily's $5000 inheritance, he ends up being right.